Lubricating oil composition, lubricating method, and transmission

ABSTRACT

Provided are a lubricating oil composition containing a mineral oil (1) having a kinematic viscosity at 100° C. of 2 mm 2 /s or more and less than 2.5 mm 2 /s, and a polymethacrylate (2) having a functional group containing an oxygen atom in the molecule while having a specific structural, unit, which satisfies both high viscosity index and high shear stability, and a lubrication method and a transmission using the lubricating oil composition.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a National Stage of PCT/JP2017/008357, which wasfiled on Mar. 2, 2017. This application is based upon and claims thebenefit of priority to Japanese Application No. 2016-042508, which wasfiled on Mar. 4, 2016.

TECHNICAL FIELD

The present invention relates to a lubricating oil composition, and to alubrication method and a transmission using the lubricating oilcomposition.

BACKGROUND ART

Recently, with the increase in the consciousness of environmentalissues, requirements for fuel saving in various technical fields arebeing severer, for the purpose of more effective use of oil resourcesand reduction in CO₂ emission. For example, for lubricating oilcompositions for use in transmissions, requirements for fuel saving areincreasing. PTL 1 proposes a lubricating oil composition obtained byblending the base oil with two kinds of polymethacrylates differing inthe molecular weight.

CITATION LIST Patent Literature

PTL 1: JP 2015-172165 A

DISCLOSURE OF INVENTION Technical Problem

For attaining fuel saving, for example, a lubricating oil compositionfor transmissions is required to satisfy the characteristics in that theviscosity thereof hardly increases so as not to increase too much thestirring resistance at low temperatures but that, on the other hand, theviscosity thereof hardly decreases so as to sufficiently maintain an oilfilm at high temperatures. The viscosity characteristics can beattained, for example, by increasing the viscosity index of alubricating oil composition, and a viscosity index improver such aspolymethacrylate as described in PTL 1 is used.

The viscosity index improving performance of a viscosity index improvergenerally bears a proportional relationship to the mean molecular weightthereof, and the performance tends to increase with the increase in themean molecular weight. On the other hand, when having a large meanmolecular weight, the molecular chain of the viscosity index improvermay be cut owing to the mechanical shear force to be given to thelubricating oil composition during use so that the performance thereofmay lower with the result that the viscosity of the lubricating oilcomposition lowers and an oil film could not be sufficiently maintainedand therefore the performance of the lubricating oil compositionworsens. Specifically, it may be said that a high viscosity index andhigh shear stability are contradictory to each other.

For attaining high fuel saving performance, a lubricating oilcomposition is required to satisfy both the contradictory properties ofhigh viscosity index and high shear stability. However, the viscosityindex improver such as a polymethacrylate as used in PTL 1 could hardlysatisfy both the contradictory properties on a higher level.

The present invention has been made in consideration of theabove-mentioned situation, and its object is to provide a lubricatingoil composition satisfying both the requirements of high viscosity indexand high shear stability, and to provide a lubrication method and atransmission using the lubricating oil composition.

Solution to Problem

As a result of assiduous studies, the present inventor has found thatthe following invention can solve the above-mentioned problems.Specifically, the present invention provides a lubricating oilcomposition having the constitution mentioned below, and a lubricationmethod and a transmission using the lubricating oil composition.

1. A lubricating oil composition containing a mineral oil (1) having akinematic viscosity at 100° C. of 2 mm²/s or more and less than 2.5mm²/s, and a polymethacrylate (2) having a functional group containingan oxygen atom in the molecule, which has a structural unit representedby the following general formula (I):

wherein R¹ represents a divalent aliphatic hydrocarbon group having 24to 40 carbon atoms, and X¹ represents a monovalent functional groupcontaining an oxygen atom.

2. A lubrication method using the lubricating oil composition of theabove 1.

3. A transmission using the lubricating oil composition of the above 1.

Advantageous Effects of Invention

According to the present invention, there are provided a lubricating oilcomposition that satisfies both high viscosity index and high shearstability, and a lubrication method and a transmission using thelubricating oil composition.

DESCRIPTION OF EMBODIMENTS

Hereinunder, embodiments of the present invention (also referred to as“the present embodiments”) are described. In this description, thenumerical values regarding “or more” and “or less” relating to thedescription of a numerical value range are values that can be combinedarbitrarily.

[Lubricating Oil Composition]

The lubricating oil composition of the present embodiment is alubricating oil composition containing a mineral oil (1) having akinematic viscosity at 100° C. of 2 mm²/s or more and less than 2.5mm²/s (hereinafter may be referred to as “mineral oil (1)”), and apolymethacrylate (2) having a functional group containing an oxygen atomin the molecule, which has a structural unit represented by theabove-mentioned general formula (I) (hereinafter may be referred to as“polymethacrylate (2)”). Each component is described below.

(Mineral Oil (1))

With no specific limitation thereon, the mineral oil may be any mineraloil whose kinematic viscosity at 100° C. falls within theabove-mentioned range. Examples of the mineral oil include topped crudesobtained through atmospheric distillation of crude oils such as paraffinbase crude oils, naphthene base crude oils or intermediate base crudeoils; distillates obtained through vacuum distillation of such toppedcrudes; mineral oils obtained by purifying the distillates through oneor more purification treatments of solvent deasphalting, solventextraction, hydrocracking, solvent dewaxing, catalytic dewaxing orhydrorefining, for example, light neutral oils, medium neutral oils,heavy neutral oils, and bright stocks; and mineral oils obtained byisomerizing wax produced through Fischer-Tropsch synthesis (GTL wax (GasTo Liquids WAX)).

As the mineral oil, those grouped in any of Groups 1, 2 and 3 in thebase oil category by API (American Petroleum Institute) may be used, butthose grouped in Groups 2 and 3 are preferred.

The kinematic viscosity at 100° C. of the mineral oil (1) is 2 mm²/s ormore and less than 2.5 mm²/s. Using one whose kinematic viscosity at100° C. falls within the above-mentioned range can readily satisfy bothhigh viscosity index and high shear stability. From the same viewpoint,the kinematic viscosity at 100° C. of the mineral oil (1) is preferably2.05 mm²/s or more, more preferably 2.1 mm²/s or more. It is alsopreferably 2.45 mm²/s or less, more preferably 2.4 mm²/s or less.

The kinematic viscosity at 40° C. of the mineral oil (1) is preferably 6mm²/s or more, more preferably 6.5 mm²/s or more, even more preferably6.8 mm²/s or more. The upper limit is preferably 11 mm²/s or less, morepreferably 10 mm²/s or less, even more preferably 9 mm²/s or less. Usingthe mineral oil (1) whose kinematic viscosity at 40° C. falls within theabove-mentioned range can readily satisfy both high viscosity index andhigh shear stability.

Also from the viewpoint of readily attaining both high viscosity indexand high shear stability, the viscosity index of the mineral oil (1) ispreferably 90 or more, more preferably 100 or more, even more preferably105 or more.

Here, the kinematic viscosity and the viscosity index are valuesmeasured using a glass capillary viscometer according to JIS K2283:2000.

The content of the mineral oil (1) based on the total amount of thelubricating oil composition is generally 50% by mass or more, preferably60% by mass or more, more preferably 65% by mass or more, even morepreferably 70% by mass or more. The upper limit is preferably 97% bymass or less, more preferably 95% by mass or less, even more preferably90% by mass or less. When the content of the mineral oil (1) fallswithin the above range, both high viscosity index and high shearstability can be readily attained.

Synthetic oils such as poly-α-olefins such as polybutene,ethylene-α-olefin copolymers, and α-olefin homopolymers or copolymers;various esters such as polyol esters, dibasic acid esters, andphosphates; various ethers such as polyphenyl ethers; polyglycols;alkylbenzenes; and alkylnaphthalenes may also be used within a range notdetracting from the advantageous effects of the present invention.

(Polymethacrylate (2))

The polymethacrylate has a structural unit represented by the followinggeneral formula (I), and therefore has a monovalent functional groupcontaining an oxygen atom in the molecule.

In the general formula (I), R¹ represents a divalent aliphatichydrocarbon group having 24 to 40 carbon atoms, and X¹ represents amonovalent functional group containing an oxygen atom. Here, when thecarbon number of R¹ is 23 or less, there may occur a problem in point ofattaining high viscosity index, and on the other hand, when the carbonnumber is 41 or more, there may occur a problem in point of attaininghigh shear stability.

The divalent aliphatic hydrocarbon group having 24 to 40 carbon atomsfor R¹ includes an alkylene group and an alkenylene group, and from theviewpoint of readily attaining high viscosity index and high shearstability, an alkylene group is preferred. The group may be linear,branched or cyclic, but from the viewpoint of more readily attainingboth high viscosity index and high shear stability, a linear or branchedgroup is preferred. Also from the same viewpoint, the carbon number ispreferably 28 to 40, more preferably 30 to 40.

Examples of the alkylene group having 24 to 40 carbon atoms includevarious tetracosylene groups such as an n-tetracosylene group, anisotetracosylene group, and isomers thereof (hereinunder functionalgroups having predetermined carbon atoms including linear and branchedones and isomers thereof may be abbreviated as various functionalgroups), various pentacosylene groups, various hexacosylene groups,various heptacosylene groups, various octacosylene groups, variousnonacosylene groups, various triacontylene groups, varioushentriacontylene groups, various dotriacontylene groups, varioustritriacontylene groups, various tetratriacontylene groups, variouspentatriacontylene groups, various hexatriacontylene groups, variousheptatriacontylene groups, various octatriacontylene groups, variousnonatriacontylene groups, and various tetracontylene groups.

In the general formula (I), X¹ represents a monovalent functional groupcontaining an oxygen atom. When the substituent is not a monovalentfunctional group containing an oxygen atom, high viscosity index andhigh shear stability could not be attained. From the viewpoint ofreadily attaining both high viscosity index and high shear stability, ahydroxy group, an alkoxy group, an aldehyde group, a carboxy group, anester group, a nitro group, an amide group, a carbamate group, a sulfogroup and the like are preferred; a hydroxy group and an alkoxy groupare more preferred; and a hydroxy group is even more preferred. Here,the alkoxy group is preferably one containing an alkyl group having 1 to30 carbon atoms, and the alkyl group may be linear or branched.

The polymethacrylate (2) may have any other structural unit representedby the following general formula (II) as far as it has the structuralunit represented by the above-mentioned general formula (I).

In the general formula (II), R² represents a divalent aliphatichydrocarbon group having 1 to 40 carbon atoms, and X² represents amonovalent functional group.

The divalent aliphatic hydrocarbon group having 1 to 40 carbon atoms forR² includes, in addition to the divalent aliphatic hydrocarbon grouphaving 24 to 40 carbon atoms exemplified for the above R¹, a divalentaliphatic hydrocarbon group having 1 to 23 carbon atoms. The divalentaliphatic hydrocarbon group having 1 to 23 carbon atoms is, from theviewpoint of readily attaining high viscosity index and high shearstability, preferably an alkylene group or an alkenylene group, morepreferably an alkylene group. The alkylene group may be linear orbranched, and more preferably has 1 to 30 carbon atoms.

Examples of the monofunctional group for X² include an aryl group suchas a phenyl group, a benzyl group, a tolyl group and a xylyl group; aheterocyclic group such as a furanyl group, a thiophenyl group, apyridinyl group and a carbazolyl group; and an organic group containinga hetero atom represented by the following general formulae (III) to(IV); and when the carbon number of R² is 1 to 23, the substituent mayfurther include a functional group containing an oxygen atom asexemplified for the above X¹, in addition to these monofunctionalgroups.

In the general formulae (III) and (IV), R³ each independently representsa hydrogen atom, or a monovalent aliphatic hydrocarbon group having 1 to30 carbon atoms. The monovalent aliphatic hydrocarbon group is, from theviewpoint of readily attaining both high viscosity index and high shearstability, preferably an alkyl group or an alkenyl group, and is morepreferably an alkyl group. The monovalent aliphatic hydrocarbon groupmay be linear or branched.

Having a structural unit represented by the above general formula (I),the polymethacrylate (2) is not specifically limited in point of theproportion of the structural unit, but from the viewpoint of morereadily attaining both high viscosity index and high shear stability,the copolymerization ratio of the structural unit represented by thegeneral formula (I) to, for example, any other structural unit than thestructural unit represented by the general formula (I) such as theabove-mentioned other structural unit (for example, the structural unitrepresented by the above general formula (II)) is preferably 10/90 to90/10, more preferably 20/80 to 80/20, even more preferably 30/70 to70/30.

The mass average molecular weight of the polymethacrylate (2) ispreferably 5,000 or more, more preferably 15,000 or more, even morepreferably 20,000 or more, especially preferably 25,000 or more. Theupper limit is preferably 100,000 or less, more preferably 80,000 orless, even more preferably 70,000 or less, especially preferably 55,000or less. When the mass average molecular weight of the polymethacrylate(2) falls within the above range, both high viscosity index and highshear stability can be more readily attained.

Here, the mass average molecular weight may be measured through gelpermeation chromatography (GPC) and determined from the calibrationcurve drawn using polystyrene. For example, the mass average molecularweight of each above-mentioned polymer may be calculated as apolystyrene-equivalent value through GPC mentioned below.

<GPC Apparatus>

Column: TOSO GMHHR-H(S)HT

Detector: RI detector for liquid chromatography, WATERS 150C

<Measurement Conditions>

Solvent: 1,2,4-trichlorobenzene

Measurement temperature: 145° C.

Flow rate: 1.0 ml/min

Sample concentration: 2.2 mg/ml

Injection amount: 160 μl

Calibration curve: Universal Calibration

Analysis program: HT-GPC (Ver. 1.0)

The content of the polymethacrylate (2) based on the total amount of thecomposition is generally 1% by mass or more, preferably 3% by mass ormore, more preferably 5% by mass or more, even more preferably 6% bymass or more, and the upper limit is generally 15% by mass or less,preferably 12% by mass or less, more preferably 10% by mass or less,even more preferably 9% by mass or less. When the content of thepolymethacrylate (2) falls within the above range, the polymethacrylateaddition effect may be sufficiently attained to readily satisfy bothhigh viscosity index and high shear stability.

(Other Additives)

In the lubricating oil composition of the present embodiment, any otheradditives than the mineral oil (1) and the polymethacrylate (2), forexample, other additive such as a viscosity index improver, anantioxidant, a metal-based detergent, a dispersant, a friction modifier,an anti-wear agent, an extreme-pressure agent, a pour point depressant,a metal deactivator, a rust inhibitor, and an anti-foaming agent may beappropriately selected and blended in the composition within a range notconflicting with the advantageous effects of the present invention. Oneof these additives may be used singly or plural kinds thereof may beused in combination. The lubricating oil composition of the presentembodiment may be composed of the mineral oil (1) and thepolymethacrylate (2) as above, or may be composed of the mineral oil(1), the polymethacrylate (2) and other additives.

Falling within a range not conflicting with the advantageous effects ofthe present invention, the total content of the additives is notspecifically limited but is, in consideration of the effect of theadditives to be added, preferably 0.1 to 20% by mass based on the totalamount of the composition, more preferably 1 to 15% by mass, even morepreferably 3 to 15% by mass.

(Viscosity Index Improver)

Examples of the viscosity index improver include polymers such asolefin-based copolymers (for example, ethylene-propylene copolymers),dispersant-type olefin-based copolymers, and styrene-based copolymers(for example, styrene-diene copolymers, and styrene-isoprenecopolymers).

(Antioxidant)

Examples of the antioxidant include amine-based antioxidants such asdiphenylamine-based antioxidants and naphthylamine-based antioxidants;phenol-based antioxidants such as monophenol-based antioxidants,diphenol-based antioxidants, and hindered phenol-based antioxidants;molybdenum-based antioxidants such as molybdenum amine complex producedthrough reaction of molybdenum trioxide and/or molybdic acid and anamine compound; sulfur-based antioxidants such as phenothiazine,dioctadecyl sulfide, dilauryl-3,3′-thiodipropionate, and2-mercaptobenzimidazole; and phosphorus-based antioxidants such asphosphite-based antioxidants such as triphenyl phosphite,diisopropylmonophenyl phosphite, and monobutyldiphenyl phosphite.

(Metal-Based Detergent)

Examples of the metal-based detergent include neutral metal sulfonates,neutral metal phenates, neutral metal salicylates, neutral metalphosphonates, basic metal sulfonates, basic metal phenates, basic metalsalicylates, basic metal phosphonates, overbased metal sulfonates,overbased metal phenates, overbased metal salicylates, and overbasedmetal phosphonates containing an alkaline earth metal such as calcium asthe metal species therein.

(Dispersant)

Examples of the dispersant include ash-free dispersants such asboron-free succinimides, boron-containing succinimides, benzylamines,boron-containing benzylamines, succinates, and mono or dicarboxylic acidamides of typically fatty acids or succinic acid.

(Friction Modifier)

Examples of the friction modifier include ash-free friction modifierssuch as fatty acid amines, fatty acid esters, fatty acid amides, fattyacids, aliphatic alcohols, and fatty acid ethers having at least onealkyl or alkenyl group having 6 to 30 carbon atoms, especially a linearalkyl or alkenyl group having 6 to 30 carbon atoms in the molecule; andmolybdenum-based friction modifiers such as molybdenum dithiocarbamate(MoDTC), molybdenum dithiophosphate (MoDTP), and molybdic acid aminesalts.

(Anti-Wear Agent)

Examples of the anti-wear agent include sulfur-containing compounds suchas zinc dialkyldithiophosphates (ZnDTP), zinc phosphate, zincdithiocarbamate, molybdenum dithiocarbamate, molybdenum dithiophosphate,disulfides, sulfurized olefins, sulfurized oils and fats, sulfurizedesters, thiocarbonates, thiocarbamates, and polysulfides;phosphorus-containing compounds such as phosphite esters, phosphateesters, phosphonate esters, and amine salts or metal salts thereof; andsulfur and phosphorus-containing anti-wear agents such asthiophosphites, thiophosphates, thiophosphonates, and amine sails ormetal salts thereof.

(Extreme-Pressure Agent)

Examples of the extreme-pressure agent include sulfur-basedextreme-pressure agents such as sulfides, sulfoxides, sulfones, andthiophosphinates; halogen-based extreme-pressure agents such aschlorohydrocarbons; and organic metal-based extreme pressure agents.

(Pour Point Depressant)

Examples of the pour point depressant include ethylene-vinyl acetatecopolymers, condensates of chloroparaffin and naphthalene, condensatesof chloroparaffin and phenol, polymethacrylates, and polyalkylstyrenes.

(Metal Deactivator)

Examples of the metal deactivator include benzotriazole compounds,tolyltriazole compounds, thiadiazole compounds, and imidazole compounds.

(Rust Inhibitor)

Examples of the rust inhibitor include petroleum sulfonates,alkylbenzene sulfonates, dinonylnaphthalene sulfonates,alkenylsuccinates, and polyalcohol esters.

(Anti-Foaming Agent)

Examples of the anti-foaming agent include silicone oils, fluorosiliconeoils, and fluoroalkyl ethers.

(Various Properties of Lubricating Oil Composition)

The kinematic viscosity at 100° C. of the lubricating oil composition ofthe present embodiment is preferably 4 mm²/s or more, more preferably4.2 mm²/s or more, even more preferably 4.5 mm²/s or more, and is alsopreferably 7 mm²/s or less, more preferably 6 mm²/s or less, even morepreferably 5.5 mm²/s or less. The kinematic viscosity at 40° C. of thelubricating oil composition of the present embodiment is preferably 10mm²/s or more, more preferably 13 mm²/s or more, even more preferably 15mm²/s or more, and is also preferably 25 mm²/s or less, more preferably22 mm²/s or less, even more preferably 20 mm²/s or less.

The viscosity index of the lubricating oil composition of the presentembodiment is preferably 232 or more, more preferably 234 or more, evenmore preferably 236 or more.

Here, the methods for measuring the kinematic viscosity and theviscosity index are the same as those for the base oil mentioned above.

Having the above-mentioned kinematic viscosity and having a highviscosity index, the lubricating oil composition of the presentembodiment has low stirring resistance and the viscosity thereof hardlyincreases at low temperatures, and on the other hand, at hightemperatures, the viscosity of the composition hardly lowers so as tosufficiently maintain an oil film.

A rate of change in kinematic viscosity at 40° C. of the lubricating oilcomposition of the present embodiment, as measured according to themethod mentioned below, is preferably 5% or less, more preferably 4.5%or less, even more preferably 4% or less. The rate of change inkinematic viscosity at 40° C. is an index of shear stability thatindicates a change of kinematic viscosity before and after ultrasonictreatment, and a smaller rate of change means that the lubricating oilcomposition is hardly influenced by ultrasonic treatment and has highershear stability. The lubricating oil composition of the presentembodiment has a small rate of change in kinematic viscosity asmentioned above, and can express high shear stability.

(Method for Calculating Rate of Change in Kinematic Viscosity at 40° C.)

With respect to an ultrasonically-treated composition obtained byirradiating a lubricating oil composition with ultrasonic waves for 60minutes according to JASO M347-95 and an untreated lubricating oilcomposition, their kinematic viscosity at 40° C. (v₁, v₀) is measuredaccording to JIS K2283:2000. The rate of reduction ((v₀−v₁)/v₀×100) isreferred to as the rate of change in kinematic viscosity at 40° C.

Regarding the lubricating oil composition of the present embodiment, inaddition, the kinematic viscosity at 100° C. of theultrasonically-treated composition and the untreated composition ismeasured and the rate of change in kinematic viscosity at 100° C.thereof is calculated according to the above-mentioned method (methodfor calculating rate of change in kinematic viscosity at 40° C.).Preferably, the thus-calculated rate of change is 8% or less, morepreferably 7% or less, even more preferably 5.5% or less.

As described above, the lubricating oil composition of the presentembodiment satisfies both high viscosity index and high shear stability,and, for example, when applied to transmissions and the like of gasolinevehicles, hybrid vehicles, electric vehicles and the like, thecomposition secures excellent fuel saving performance and is thereforefavorably used for these uses. In addition, the lubricating oilcomposition is also favorably used for other uses, for example, forinternal combustion engines, hydraulic machinery, turbines, compressors,working machines, cutting machines, gears, and machines equipped withliquid bearings or ball bearings.

[Lubrication Method and Transmission]

The lubrication method of the present embodiment is a lubrication methodusing the lubricating oil composition of the present embodimentdescribed above. The lubricating oil composition for use in thelubrication method of the present embodiment satisfies both highviscosity index and high shear stability. Accordingly, the lubricationmethod of the present embodiment is favorably used, for example, fortransmissions of gasoline vehicles, hybrid vehicles, electric vehiclesand the like, and when used in these uses, the method exhibits excellentfuel saving performance. In addition, the lubrication method is alsofavorably used for other uses, for example, for lubrication of internalcombustion engines, hydraulic machinery, turbines, compressors, workingmachines, cutting machines, gears, and machines equipped with liquidbearings or ball bearings.

The transmission of the present embodiment uses the lubricating oilcomposition of the present embodiment. The transmission of the presentembodiment expresses excellent fuel saving performance and is widelyfavorably applied to various vehicles such as gasoline vehicles, hybridvehicles and electric vehicles.

EXAMPLES

Next, the present invention is described in more detail with referenceto Examples, but the present invention is not limited at all by theseExamples.

Examples 1 to 3, Comparative Examples 1 and 2

Lubricating oil compositions were prepared at the blending ratio (% bymass) shown in Table 1. The resultant lubricating oil compositions weretested variously according to the methods mentioned below to evaluatethe properties thereof. The evaluation results are shown in Table 1.Details of each component shown in Table 1 used in these Examples are asfollows.

Mineral oil: 60 N (neutral) hydrorefined mineral oil, kinematicviscosity at 100° C.: 2.17 mm²/s, kinematic viscosity at 40° C.: 7.12mm²/s, viscosity index: 109, API Group 2.

PMA-A: polymethacrylate having a functional group containing an oxygenatom in the molecule (having a structural unit represented by thegeneral formula (I) where R¹ is at least one selected from an alkylgroup having 24 to 40 carbon atoms, and X¹ is a hydroxy group), massaverage molecular weight: 30,000.

PMA-B: polymethacrylate having a functional group containing an oxygenatom in the molecule (having a structural unit represented by thegeneral formula (I) where R¹ is at least one selected from an alkylgroup having 24 to 40 carbon atoms, and X¹ is a hydroxy group), massaverage molecular weight: 35,000.

PMA-C: polymethacrylate having a functional group containing an oxygenatom in the molecule (having a structural unit represented by thegeneral formula (I) where R¹ is at least one selected from an alkylgroup having 24 to 40 carbon atoms, and X¹ is a hydroxy group), massaverage molecular weight: 50,000.

PMA-D: polymethacrylate not having a functional group containing anoxygen atom in the molecule, mass average molecular weight: 30,000.

PMA-E: polymethacrylate not having a functional group containing anoxygen atom in the molecule, mass average molecular weight: 200,000.

Other additives: phenol-based antioxidant, metal-based detergent(overbased calcium sulfonate), dispersant (boron-freepolybutenylsuccinic acid bisimide, boron-containing polybutenylsuccinicacid monoimide), friction modifier (fatty acid amine, fatty acid amide).

The properties of the lubricating oil compositions were measuredaccording to the following methods.

(1) Kinematic Viscosity

The kinematic viscosity at 40° C. and 100° C. was measured according toJIS K 2283:2000.

(2) Viscosity Index (VI)

Measured according to JIS K 2283:2000.

(3) Calculation of Rate of Change in Kinematic Viscosity

With respect to the ultrasonically-treated composition obtained byirradiating a lubricating oil composition with ultrasonic waves for 60minutes according to JASO M347-95 and an untreated lubricating oilcomposition, their kinematic viscosity at 40° C. (v₁, v₀) was measuredaccording to JIS K2283:2000. The rate of reduction ((v₀−v₁)/v₀×100) wascalculated, and this is referred to as the rate of change in kinematicviscosity at 40° C. The rate of reduction ((v₀−v₁)/v₀×100) wascalculated, and this is referred to as the rate of change in kinematicviscosity at 40° C. In place of the kinematic viscosity at 40° C., thekinematic viscosity at 100° C. was measured, and the rate of change inkinematic viscosity at 100° C. was calculated.

TABLE 1 Comparative Example Example 1 2 3 1 2 Mineral Oil (1) (% bymass) balance balance balance balance balance Polymethacrylate (2) PMA-A(% by mass) 8.00 — — — — PMA-B (% by mass) — 7.50 — — — PMA-C (% bymass) — — 7.25 — — PMA-D (% by mass) — — — 7.20 — PMA-E (% by mass) — —— — 3.00 Other Additives (% by mass) 11.50 11.50 11.50 11.50 11.50Before Ultrasonic Treatment Kinematic Viscosity at 40° C. (mm²/s) 17.617.5 17.2 18.0 16.0 Kinematic Viscosity at 100° C. (mm²/s) 5.00 5.005.00 5.00 5.00 Viscosity Index — 239 241 249 230 279 After UltrasonicTreatment Kinematic Viscosity at 40° C. (mm²/s) 17.3 17.0 16.6 17.5 13.0Kinematic Viscosity at 100° C. (mm²/s) 4.93 4.88 4.76 4.89 3.60 Rate ofChange in Kinematic (%) 1.70 2.86 3.49 2.78 18.8 Viscosity at 40° C.Rate of Change in Kinematic (%) 1.40 2.40 4.80 2.20 28.0 Viscosity at100° C.

The results of Examples 1 to 3 confirm that the lubricating oilcompositions of the present embodiment all have a high viscosity indexof 239, 241 or 249, and the rate of change in kinematic viscosity at 40°C. thereof was 1.70%, 2.86% or 3.49% and was extremely small, and thus,the lubricating oil compositions satisfy both high viscosity index andhigh shear stability. On the other hand, regarding the lubricating oilcomposition of Comparative Example 1 using a polymethacrylate not havinga functional group containing an oxygen atom, the rate of change inkinematic viscosity at 40° C. thereof was 2.78% and was small, but theviscosity index thereof was 230 and was lower than in Examples 1 to 3,that is, the comparative composition could not be said to have a highviscosity index. When Comparative Example 1 is compared with Example 1using a polymethacrylate having the same mass average molecular weight,the rate of kinematic viscosity reduction in the former is large, thatis, the comparative composition could not be said to have high shearstability.

The lubricating oil composition of Comparative Example 2 using apolymethacrylate not having a functional group containing an oxygenatom, whose mass average molecular weight was larger than that used inComparative Example 1, had a high viscosity index of 279, but the rateof change in kinematic viscosity at 40° C. thereof was 18.8% and waslarge, that is, the comparative composition could not be said to havehigh shear stability.

INDUSTRIAL APPLICABILITY

The lubricating oil composition and the lubrication method of thepresent invention is favorably used for transmissions of gasolinevehicles, hybrid vehicles, electric vehicles and the like. Thetransmission of the present invention is favorably used as atransmission of gasoline vehicles, hybrid vehicles and electricvehicles.

The invention claimed is:
 1. A lubricating oil composition, comprising:a mineral oil having a kinematic viscosity at 100° C. of 2 mm²/s or moreand less than 2.5 mm²/s; and a polymethacrylate having a functionalgroup comprising an oxygen atom in the molecule, wherein thepolymethacrylate has a structural unit of formula (I),

where R¹ is a divalent aliphatic hydrocarbon group having 24 to 40carbon atoms, and X¹ is a hydroxyl group, and the polymethacrylate has amass average molecular weight in a range of 20,000 to 70,000, and acontent 5% by mass to 15% by mass based on the total amount of thelubricating oil composition.
 2. The lubricating oil compositionaccording to claim 1, wherein the mass average molecular weight of thepolymethacrylate is in a range of 25,000 to 70,000.
 3. The lubricatingoil composition according to claim 1, wherein the content of thepolymethacrylate is in a range of 5% by mass to 12% by mass based on thetotal amount of the lubricating oil composition.
 4. The lubricating oilcomposition according to claim 1, wherein the lubricating oilcomposition is formulated to have a kinematic viscosity at 100° C. in arange of 4 mm²/s to 7 mm²/s.
 5. The lubricating oil compositionaccording to claim 1, wherein the lubricating oil composition isformulated to have a viscosity index of 232 or more.
 6. The lubricatingoil composition according to claim 1, wherein the lubricating oilcomposition is formulated to have a rate of change in kinematicviscosity at 40° C. of 5% or less, as calculated with respect to anultrasonically-treated composition obtained by irradiating thelubricating oil composition with ultrasonic waves for 60 minutesaccording to JASO M347-95 and an untreated lubricating oil composition,their kinematic viscosity at 40° C. (v₁, v₀) being measured according toJIS K2283:2000, and where a rate of reduction ((v₀−v₁)/v₀×100) is a rateof change in kinematic viscosity at 40° C.
 7. The lubricating oilcomposition according to claim 1, wherein the lubricating oilcomposition is formulated to have a kinematic viscosity at 100° C. in arange of 4 mm²/s to 7 mm²/s and a viscosity index of 232 or more.
 8. Alubrication method, comprising: applying the lubricating oil compositionof claim 1 to a device.
 9. The lubrication method according to claim 8,wherein the device is a transmission.
 10. A transmission, comprising, atransmission device; and the lubricating oil composition of claim
 1. 11.The lubricating oil composition according to claim 1, wherein thekinematic viscosity of the mineral oil at 100° C. is in a range of 2mm²/s 2.4 mm²/s.
 12. The lubricating oil composition according to claim1, Wherein the mass average molecular weight of the polymethacrylate isin a range of 25,000 to 55,000.
 13. The lubricating oil compositionaccording to claim 1, wherein the content of the polymethacrylate is ina range of 6% by mass to 10% by mass based on the total amount of thelubricating oil composition.
 14. The lubricating oil compositionaccording to claim 2, wherein the lubricating oil composition isformulated to have a kinematic viscosity at 100° C. in a range of 4mm²/s to 7 mm²/s.
 15. The lubricating oil composition according to claim2, wherein the lubricating oil composition is formulated to have aviscosity index of 232 or more.
 16. The lubricating oil compositionaccording to claim 2, wherein the lubricating oil composition isformulated to have a rate of change in kinematic viscosity at 40° C. of5% or less, as calculated with respect to an ultrasonically-treatedcomposition obtained by irradiating the lubricating oil composition withultrasonic waves for 60 minutes according to JASO M347-95 and anuntreated lubricating oil composition, their kinematic viscosity at 40°C. (v₁, v₀) being measured according to JIS K2283:2000, and where a rateof reduction ((v₀−v₁)/v₀×100) is a rate of change in kinematic viscosityat 40° C.
 17. The lubricating oil composition according to claim 2,wherein the lubricating oil composition is formulated to have akinematic viscosity at 100° C. in a range of 4 mm²/s to 7 mm²/s and aviscosity index of 232 or more.
 18. The lubricating oil compositionaccording to claim 1 wherein the polymethacrylate further includes astructural unit of formula (II),

where R² is a divalent aliphatic hydrocarbon group having 1 to 40 carbonatoms, and X² is a monovalent functional group.
 19. The lubricating oilcomposition according to claim 1 further comprising: a dispersant. 20.The lubricating oil composition according to claim 3, wherein thelubricating oil composition is formulated to have a kinematic viscosityat 100° C. in a range of 4 mm²/s to 7 mm²/s.